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Chemical bonding.

Salt shatters, copper bends and diamond scratches glass. Slide one layer of atoms over the next and see how the way atoms hold on decides which.

Explore the scene Interactive article

01 / The experiment

Push the top half and see what holds.

Choose a bond type, slide the top half of the crystal along by one step, then look inside at the atoms.

Still of the Chemical bonding 3D scene, which explores: Why does a salt crystal shatter when a copper wire just bends?
Interactive scene

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The explanation below is available while the scene loads.

Real structures and spacings for rock salt, copper and diamond. Sliding moves the top half along one plane of atoms; a crack opens where the arrangement can no longer hold.Ions and atoms are drawn at about half their true size. The glowing electrons in copper are a picture of shared electrons, not tracked particles, and the crystal heals when you slide back, which a real crack would not.

02 / Three bonds

Give, pool or share.

Where the outer electrons go decides how a solid behaves.

Table salt
+−+−+−+−+−+−+−+−+−+−

Ionic

Sodium hands an electron to chlorine. The charged ions that result attract every neighbour of the opposite sign, in a strict alternating pattern.

Made of
Na⁺ and Cl⁻ ions
Held by
Pull between opposite charges
Pushed
Splits along a plane
Conducts
Only melted or dissolved
Copper wire

Metallic

Each atom lets go of an outer electron. The freed electrons roam the whole metal and glue the positive ions together wherever they move.

Made of
Cu ions and free electrons
Held by
A shared sea of electrons
Pushed
Bends and stretches
Conducts
Yes, very well
Diamond

Covalent

Neighbouring atoms share pairs of electrons in bonds that point in fixed directions. In diamond those bonds join the whole crystal into one molecule.

Made of
Carbon atoms
Held by
Shared electron pairs
Pushed
Resists, then cracks
Conducts
No
The big idea

Atoms bond by handing over electrons, pooling them or sharing them in pairs. That one choice explains why salt shatters, copper bends and diamond is hard.

NaCl · Cu · C

Three ways to hold on

Tap a salt crystal with a hammer and it shatters into smaller cubes. Tap a copper wire and it bends. Drag a diamond across glass and it leaves a scratch. All three are solids made of atoms packed in a regular pattern. What differs is the chemical bond: how the electrons that sit between atoms hold them together. Almost every bond is some mix of three simple kinds: ionic, metallic and covalent.

Ionic: give and take

Sodium holds its one outer electron loosely; chlorine pulls hard on electrons. When they meet, the electron moves across, leaving a positive sodium ion, Na⁺, and a negative chloride ion, Cl⁻. Opposite charges attract, so in salt every ion is surrounded by six of the other kind. There is no single partner and no shared pair: the whole crystal is held by the pull between all the opposite charges at once. That pull is strong. Salt does not melt until 801 °C.

It is also why salt is brittle. Slide one layer of ions along by one ion’s width and every ion now faces one with the same charge. Like charges repel, and the crystal splits cleanly along that plane. Solid salt does not conduct electricity either, because its ions are locked in place; melted or dissolved in water, the ions move freely and it conducts.

Metallic: a sea of electrons

A metal’s atoms each let go of one or two outer electrons, which no longer belong to any one atom. They roam through the whole crystal, a sea of shared electrons holding a lattice of positive ions together. Push a voltage across the metal and these electrons drift along it: that is an electric current, and it is why copper is one of the best conductors there is.

Slide one layer of copper ions over the next and nothing breaks. The ions move to new neighbours, and the sea of electrons simply flows around them and holds them there too. That is why metals bend, hammer flat into sheets and draw out into wires instead of shattering.

Try it: choose Ionic: salt and slide Slide the top half to 1 step, then choose Metallic: copper and do the same. Choose Atoms under Zoom to the atoms to see why one splits and the other only bends.

Back to the experiment

Covalent: sharing pairs

Carbon atoms neither give electrons away nor set them free; they share them. Each covalent bond is a pair of electrons held between two atoms, pointing in a fixed direction. In diamond every carbon shares a pair with each of four neighbours, at the corners of a tetrahedron, 0.154 nanometres away. The result is one giant molecule as big as the whole crystal.

To bend diamond you would have to stretch those bonds, and they do not stretch far. Push hard enough and they snap instead, so diamond is very hard but still brittle. Every electron is tied up in a bond, so diamond does not conduct electricity. Smaller molecules such as water use the same kind of bond, but only inside each molecule.

What this model leaves out

Real bonds are rarely purely one kind: the bond in water is covalent but lopsided, with the oxygen pulling the shared pair closer. The slide here moves a whole half of the crystal at once. Real metals bend by moving one line defect at a time, called a dislocation, which is why they bend at forces far below what this picture suggests. Real cracks also start at tiny flaws, and once open they stay open.

Reuse with credit to ViewWiki and a link to this page.

04 / Learn this in a course

Practise it, step by step.

This lesson teaches the topic with checked questions.

  1. Ionic and metallic lattices Chemistry · Bonding and structure