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Lesson 4 of 4

Dilution and separation.

About 25 minutes · 6 practice questions

What changes when you add water to a solution and what stays the same, and how to take a mixture apart again: filtering, evaporation, crystallisation and distillation.

Step 1 of 6 · A sample

Step 1 of 6

A sample

A solution is uniform: its concentration is the same everywhere in it. So if you take a sample of it, with a spoon or a pipette, the sample has the same concentration as the whole solution, even though it holds less solute.

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Step 2 of 6

Dilution

Diluting means adding solvent to a solution. The moles of solute do not change, but they spread through a bigger volume, so the concentration falls. Since n=cVn = cV⁠ stays the same,

c1V1=c2V2c_1 V_1 = c_2 V_2⁠

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Step 3 of 6

How much water

The same equation tells you what volume to dilute to: V2=c1V1c2V_2 = \dfrac{c_1 V_1}{c_2}⁠. The water you add is V2−V1V_2 - V_1⁠.

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Step 4 of 6

Filtering

A mixture can be taken apart again, because each part keeps its own properties. Filtering separates an undissolved solid from a liquid: the crystals stay on the filter paper, and the liquid passes through. The glass now holds 45 g of salt at 20 °C: some dissolved, some in a pile. Evaporating the liquid that passed through gives back the solute.

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Step 5 of 6

Crystallisation

Another way to get a solid out of a solution is crystallisation: dissolve it in hot water, then cool it. As the solubility falls, the excess comes out of solution as pure crystals. The glass holds 39 g of salt that all dissolved in boiling water, and now the solution has been cooled to 20 °C.

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Step 6 of 6

Distillation

To keep the solvent instead, use distillation: boil the solution, lead the steam through a cooled tube, and collect the liquid that condenses in another vessel. The solute, whose boiling point is much higher, stays behind. In the Scene the water is at 373 K.

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Interactive scene

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Each step sets up the Scene for you, and a control marked “fixed” stays put for that step.

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Practice · Choose

A glass holds 100 mL of salt solution at 2.0 mol/L. Half of it is poured into another glass. What is the concentration in the new glass?

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Practice · Calculate

You take 10 mL of a 2.0 mol/L solution and add water up to 100 mL. What is the new concentration?

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Practice · Calculate

You have 50 mL of a 1.0 mol/L solution and need a 0.25 mol/L one. To what volume must you dilute it?

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Practice · Calculate

The glass holds 45 g of salt in 100 g of water at 20 °C. You filter the mixture, then evaporate all the water from the filtrate, the liquid that came through the filter. How many grams of salt are left in the dish?

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Practice · Calculate

39 g of salt has all dissolved in 100 g of boiling water. The solution is cooled to 20 °C. How many grams of crystals come out?

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Practice · Choose

How do you get fresh water, with no salt, from seawater?