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Crystals.

Salt grains are tiny cubes and snowflakes have six arms. Zoom to the atoms a crystal for its repeating pattern, and see why slow cooling grows big ones.

Explore the scene Interactive article

01 / The experiment

Slow and large, fast and small.

Pick a crystal and change the cooling rate, then look inside to find the cell that repeats.

Still of the Crystals 3D scene, which explores: Why does table salt come out as tiny cubes?
Interactive scene

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The explanation below is available while the scene loads.

Crystal sizes come from a nucleation-and-growth model. New seeds appear faster the further the liquid falls below its freezing point, and every crystal grows until it meets its neighbours.The cooling rate is relative, not degrees per second. Crystals are drawn in their ideal shapes, atoms at about half their true size, and their thermal jiggle is exaggerated so it shows.

02 / Three cooling speeds

One melt, three rocks.

The same molten rock grows big crystals, small ones or none, depending on how fast it cools.

Cooled deep underground

Granite

Buried magma loses heat slowly through the rock around it. Few seeds form and each grows large, so you can see the separate crystals by eye.

Cooled
Slowly, over thousands of years or more
Crystals
Millimetres to centimetres
Seen in
Worktops, the cores of mountains
Cooled at the surface

Basalt

Lava meets air or water and cools fast. Seeds form everywhere at once and crowd each other, so the rock looks almost smooth and grey.

Cooled
Quickly, in days to years
Crystals
Mostly under a millimetre
Seen in
Ocean floors, lava flows
Cooled almost at once

Obsidian

Some lava cools so fast that its atoms freeze in place before they can line up. The result is a glass, which breaks along smooth curves instead of crystal faces.

Cooled
Very fast
Crystals
Almost none: a glass
Seen in
Volcanic glass, stone blades
The big idea

A crystal is a pattern of atoms that repeats. How large crystals grow is a race between new seeds forming and existing crystals growing: cool slowly and growth wins, cool fast and the seeds win.

NaCl

Order you can see

Pour some table salt onto dark paper and look closely, with a magnifying glass if you have one. Most grains are little cubes with flat faces and sharp corners. Nobody cut them that way. Snowflakes have six arms, quartz grows as six-sided columns with pointed tips, and a split geode is lined with glittering points. A crystal is a solid whose shape comes from inside: its atoms are stacked in a pattern that repeats, identically, in every direction.

One small box, repeated

Choose Atoms under Zoom to the atoms. In salt, sodium and chloride ions alternate along every row, every column and every layer, each sodium surrounded by six chlorides and each chloride by six sodiums. The smallest block that builds the whole crystal by copying itself is the unit cell. For salt it is a cube 0.564 nanometres along each edge, so a grain one millimetre across is nearly two million cells wide.

The shape of the cell shows up in the shape of the crystal. Salt’s cell is a cube, and the flat faces of a grain are planes of ions lying exactly along that cube. Ice is built from water molecules linked by hydrogen bonds into puckered hexagonal rings, which is why every snowflake has six-fold symmetry. Quartz winds its silicon and oxygen atoms in spirals around three-fold axes, and grows six-sided columns.

Switch on Show unit cell and compare the outlined cell for Salt, Ice and Quartz with the shape of their crystals.

Seeds and growth

A crystal starts as a seed: a few atoms that happen to settle into the right arrangement. Below its freezing point a liquid is ready to crystallise, but a seed that is too small simply falls apart again. The colder the liquid gets below its freezing point, the smaller a seed needs to be to survive, and the faster new ones appear. Meanwhile every seed that does survive grows, adding layer after layer of atoms to its faces.

How big the finished crystals are depends on which wins. Cool a melt slowly and the first few seeds have time to grow through all the liquid before many more appear: a few large crystals. Cool it fast and the liquid sinks far below its freezing point while it is still mostly liquid, seeds appear everywhere at once, and they crowd each other out before any grows large.

Try it: move Cooling rate from 1 to 100 × slowest and count the crystals. The same amount of material ends up in a few big ones or a crowd of small ones.

Back to the experiment

Crystals everywhere

Rocks record this. Granite cooled deep underground over thousands of years or more, and its crystals are big enough to see. Basalt is lava that cooled at the surface within days to years; its crystals are mostly too small to pick out. Obsidian cooled so fast that hardly any crystals formed at all: it is a glass. Geodes fill slowly from mineral-rich water, so their quartz has time to grow into long points. Metals are crystals too. A steel beam or a copper wire is a mosaic of tiny crystal grains, and metalworkers control their size by how quickly the metal cools.

What this model leaves out

The crystals here grow on a flat rock, and their sizes come from a simple nucleation-and-growth calculation that is honest about the trend, not about real times or temperatures. Real grains fill space and meet along irregular boundaries rather than as perfect cubes and columns. Salt usually crystallises as water evaporates rather than as a melt cools, but the same competition between new seeds and growing crystals decides its size. Real ice arranges its hydrogens in a disordered way that still obeys the same rules, rather than the single tidy pattern drawn here.

Reuse with credit to ViewWiki and a link to this page.

04 / Learn this in a course

Practise it, step by step.

These 2 lessons teach the topic with checked questions, in course order.

  1. Ionic and metallic lattices Chemistry · Bonding and structure
  2. Crystals Chemistry · Bonding and structure