ViewWiki

Lesson 3 of 4

Neutralisation and titration.

About 30 minutes · 5 practice questions

An acid and a base that give a salt and water, a pH curve that leaps near the equivalence point, and titrating drop by drop to measure an unknown concentration.

Step 1 of 5 · Neutralisation

Step 1 of 5

Neutralisation

When an acid meets a base, the hydronium and hydroxide ions join into water:

H3O++OH−→2H2O\mathrm{H_3O^+ + OH^- \rightarrow 2H_2O}⁠

That reaction is called neutralisation. On the bench in the Scene a titration is set up: the conical flask holds 25 mL of hydrochloric acid with a few drops of phenolphthalein, an indicator that is colourless in acid and pink in base. The burette above it holds sodium hydroxide. The tap at the bottom of the burette lets it run, and a magnet turning under the flask stirs it. Volume added says how much base has run out of the burette, and the Drop by drop chart draws the pH.

To the question

Step 2 of 5

The curve

Here Volume added and Look inside are fixed. Predict, then run it.

To the question

Step 3 of 5

The equivalence point

The point at which the acid and the base added hold exactly the same number of moles is called the equivalence point. There:

caVa=cbVbc_a V_a = c_b V_b⁠

Now the flask holds 20 mL of acid, and the base in the burette is more dilute: 0.08 mol/L. The readings beside the Scene show both solutions.

To the question

Step 4 of 5

Running it in

In a real titration you open the tap quickly at first, and slowly, drop by drop, near the equivalence point. Volume added moves in steps of 0.1 mL, about one drop.

To the question

Step 5 of 5

An acid of unknown concentration

That is titration’s main use: measuring an unknown concentration. You fill the burette with a solution of known concentration, titrate until the colour flips, and read off how much ran out. Here Look inside is open at Whole curve, and the readings do not show the acid’s concentration.

To the question

Interactive scene

Loading the interactive version…

Each step sets up the Scene for you, and a control marked “fixed” stays put for that step.

To the experiment

Practice · Choose

The flask holds hydrochloric acid, and the burette sodium hydroxide. What forms when they react?

To the experiment

Practice · Predict, then look

The flask holds 25 mL of hydrochloric acid, and the burette sodium hydroxide, both at 0.1 mol/L. How will the pH change as you add up to 30 mL?

To the experiment

Practice · Calculate

Now the flask holds 20 mL of 0.10 mol/L hydrochloric acid, and the burette 0.08 mol/L sodium hydroxide. What volume of base will exactly neutralise all the acid?

To the experiment

Practice · Reach the target

Again 25 mL of hydrochloric acid and sodium hydroxide, both at 0.1 mol/L. Change Volume added until you have added exactly enough base to neutralise all the acid, then press Check.

To the experiment

Practice · Calculate

The flask holds 25.0 mL of hydrochloric acid of unknown concentration, and the burette 0.100 mol/L sodium hydroxide. Look inside at Whole curve shows the equivalence point. What is the acid’s concentration?