An acid and a base that give a salt and water, a pH curve that leaps near the equivalence point, and titrating drop by drop to measure an unknown concentration.
Step 1 of 5 · Neutralisation
Step 1 of 5
Neutralisation
When an acid meets a base, the hydronium and hydroxide ions join into water:
That reaction is called neutralisation. On the bench in the Scene a titration is set up: the conical flask holds 25 mL of hydrochloric acid with a few drops of phenolphthalein, an indicator that is colourless in acid and pink in base. The burette above it holds sodium hydroxide. The tap at the bottom of the burette lets it run, and a magnet turning under the flask stirs it. Volume added says how much base has run out of the burette, and the Drop by drop chart draws the pH.
Step 2 of 5
The curve
Here Volume added and Look inside are fixed. Predict, then run it.
Step 3 of 5
The equivalence point
The point at which the acid and the base added hold exactly the same number of moles is called the equivalence point. There:
Now the flask holds 20 mL of acid, and the base in the burette is more dilute: 0.08 mol/L. The readings beside the Scene show both solutions.
Step 4 of 5
Running it in
In a real titration you open the tap quickly at first, and slowly, drop by drop, near the equivalence point. Volume added moves in steps of 0.1 mL, about one drop.
Step 5 of 5
An acid of unknown concentration
That is titration’s main use: measuring an unknown concentration. You fill the burette with a solution of known concentration, titrate until the colour flips, and read off how much ran out. Here Look inside is open at Whole curve, and the readings do not show the acid’s concentration.
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Each step sets up the Scene for you, and a control marked “fixed” stays put for that step.
Practice · Choose
The flask holds hydrochloric acid, and the burette sodium hydroxide. What forms when they react?
Practice · Choose
The flask holds hydrochloric acid, and the burette sodium hydroxide. What forms when they react?
Practice · Predict, then look
The flask holds 25 mL of hydrochloric acid, and the burette sodium hydroxide, both at 0.1 mol/L. How will the pH change as you add up to 30 mL?
Practice · Predict, then look
The flask holds 25 mL of hydrochloric acid, and the burette sodium hydroxide, both at 0.1 mol/L. How will the pH change as you add up to 30 mL?
Practice · Calculate
Now the flask holds 20 mL of 0.10 mol/L hydrochloric acid, and the burette 0.08 mol/L sodium hydroxide. What volume of base will exactly neutralise all the acid?
Practice · Calculate
Now the flask holds 20 mL of 0.10 mol/L hydrochloric acid, and the burette 0.08 mol/L sodium hydroxide. What volume of base will exactly neutralise all the acid?
Practice · Reach the target
Again 25 mL of hydrochloric acid and sodium hydroxide, both at 0.1 mol/L. Change Volume added until you have added exactly enough base to neutralise all the acid, then press Check.
Practice · Reach the target
Again 25 mL of hydrochloric acid and sodium hydroxide, both at 0.1 mol/L. Change Volume added until you have added exactly enough base to neutralise all the acid, then press Check.
Practice · Calculate
The flask holds 25.0 mL of hydrochloric acid of unknown concentration, and the burette 0.100 mol/L sodium hydroxide. Look inside at Whole curve shows the equivalence point. What is the acid’s concentration?
Practice · Calculate
The flask holds 25.0 mL of hydrochloric acid of unknown concentration, and the burette 0.100 mol/L sodium hydroxide. Look inside at Whole curve shows the equivalence point. What is the acid’s concentration?
Lesson complete. Every practice question here is done.