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Lesson 5 of 5

Hydrogen, oxygen and nitrogen.

About 20 minutes · 4 practice questions

Three colourless, odourless gases, and one test that tells them apart: a burning splint. And inside the jar: why hydrogen molecules move four times as fast as oxygen’s.

Step 1 of 5 · The splint test

Step 1 of 5

The splint test

Hydrogen, oxygen and nitrogen are colourless, odourless gases, and in a closed jar you cannot tell them apart by looking. In the lab they are told apart by what they do to a flame. In the Scene a burning splint is brought to the mouth of a jar full of air, and it keeps burning quietly.

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Step 2 of 5

The pop

Hydrogen is a flammable gas: it burns in oxygen. When the splint reaches the mouth of the jar, the hydrogen escaping from it mixes with the air and catches all at once, with a small pop. That is the test for hydrogen. Look at what is left on the glass after the pop.

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Step 3 of 5

Nitrogen

In nitrogen the splint goes out. Nitrogen does not burn and does not support burning, because its molecule, N2\mathrm{N_2}⁠, holds its two atoms in a very strong triple bond. It is the gas that makes up about 78% of the air, which is why wood burns gently in air: only about a fifth of the molecules that hit it are oxygen.

Change Gas in the jar between the four options, and compare.

Step 4 of 5

Inside the jar

Zoom to the molecules is at Molecules: the jar has been closed, with hydrogen molecules inside. In a gas the average kinetic energy of a molecule depends only on the temperature, 32kT\tfrac32 kT⁠. From that you can work out the average speed:

vˉ=8RTπM\bar v = \sqrt{\frac{8RT}{\pi M}}⁠

where MM⁠ is the molar mass in kilograms per mole.

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Step 5 of 5

Light and fast

At the same temperature every gas has the same average kinetic energy, 12mv2\tfrac12 m v^2⁠. So a light molecule moves faster: the speed goes inversely as the square root of the mass, vˉ∝1M\bar v \propto \dfrac{1}{\sqrt M}⁠. The jar now holds oxygen; compare its speed in the table beside the Scene with hydrogen’s.

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Still of the Hydrogen, oxygen, nitrogen 3D scene
Interactive scene

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Each step sets up the Scene for you, and a control marked “fixed” stays put for that step.

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Practice · Predict, then look

The jar holds air now, and the burning splint keeps burning quietly in it. What will the splint do in a jar of pure Oxygen?

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Practice · Choose

At a jar of hydrogen the splint gives a pop, and a thin mist is left on the glass. What is it?

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Practice · Calculate

The jar holds hydrogen at 293 K. The average speed of gas molecules is vˉ=8RTπM\bar v = \sqrt{\dfrac{8RT}{\pi M}}⁠, with MM⁠ in kilograms per mole. For hydrogen M=0.002016 kg/molM = 0.002016\ \mathrm{kg/mol}⁠. What is the average speed?

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Practice · Calculate

The molar mass of oxygen, O2\mathrm{O_2}⁠, is 32 g/mol, and of hydrogen, H2\mathrm{H_2}⁠, 2 g/mol. At the same temperature, how many times faster are the hydrogen molecules?