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Answer key · Unit 9

Acids and bases.

Each lesson’s practice questions, their correct answers and the mistakes they spot. Answers read off the Scene use the same setting the learner sees.

Lesson 1 of 4 · About 20 minutes

Acids, bases and ions in water

What makes a solution acidic or basic: hydronium and hydroxide ions, water that splits by itself, and the difference between a strong acid and a concentrated one.

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The 5 steps and their answers
  1. Step 1 of 5

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    Two ions

    Practice · Choose

    Question

    pH stands at 3. What is true about the ions in the beaker?

    Correct answer

    • Correct It holds both H3O+\mathrm{H_3O^+}⁠ and OH−\mathrm{OH^-}⁠, but far more H3O+\mathrm{H_3O^+}⁠

    Setup, choices and feedback

    The Scene at this step

    pH
    3
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    Choices

    Shown in a random order.

    • Correct It holds both H3O+\mathrm{H_3O^+}⁠ and OH−\mathrm{OH^-}⁠, but far more H3O+\mathrm{H_3O^+}⁠

    • Wrong It holds only H3O+\mathrm{H_3O^+}⁠, and no OH−\mathrm{OH^-}⁠ at all

      Misconception: Thinks an acidic solution holds no OH⁻ at all, or a basic one no H₃O⁺.

      Feedback from the catalogue

      Every solution in water holds both hydronium ions, H3O+\mathrm{H_3O^+}⁠, and hydroxide ions, OH−\mathrm{OH^-}⁠, because water itself is always splitting a little. What makes a solution acidic is which there is more of: in an acidic solution [H3O+]>[OH−][\mathrm{H_3O^+}] > [\mathrm{OH^-}]⁠, and always [H3O+][OH−]=10−14[\mathrm{H_3O^+}][\mathrm{OH^-}] = 10^{-14}⁠ at 25 °C.

    • Wrong It holds equal amounts of the two ions, but more acid

      Feedback

      Equal amounts of H3O+\mathrm{H_3O^+}⁠ and OH−\mathrm{OH^-}⁠ are what defines a neutral solution, at pH 77⁠.

    Feedback for a right answer

    At pH 33⁠ there are 10−310^{-3}⁠ moles of H3O+\mathrm{H_3O^+}⁠ and 10−1110^{-11}⁠ moles of OH−\mathrm{OH^-}⁠ per litre: a hundred billion times as many, but not zero. An acid is a substance that gives H3O+\mathrm{H_3O^+}⁠ ions in water, and a base gives OH−\mathrm{OH^-}⁠.

    Hint

    The second chart shows both ions, each on its own bar.

    Worked solution

    1. Water always holds both ions, because water splits: 2H2O⇌H3O++OH−\mathrm{2H_2O \rightleftharpoons H_3O^+ + OH^-}⁠.
    2. An acid adds H3O+\mathrm{H_3O^+}⁠, and the equilibrium shifts left: OH−\mathrm{OH^-}⁠ thins out, but does not vanish.
    3. [H3O+][OH−]=10−14[\mathrm{H_3O^+}][\mathrm{OH^-}] = 10^{-14}⁠, so when one grows, the other shrinks.
  2. Step 2 of 5

    Open this step

    Pure water

    Practice · Calculate

    Question

    In pure water at 25 °C the pH is 77⁠. What is the concentration of H3O+\mathrm{H_3O^+}⁠ ions?

    Correct answer

    1 × 10⁻⁷ mol/L ± 3%

    Setup, choices and feedback

    The Scene at this step

    pH
    7fixed
    Labels
    offdefault
    Fade the water
    Off
    Accepted within
    ± 3%
    Computed from the Scene at this step’s setting
    'acid-base': H₃O⁺ concentration (10^−pH mol/L)/nodes/beaker/outputs/hydronium

    Any unit of the same quantity is accepted; it is converted before checking.

    Wrong answers it recognises

    • 0 mol/L ± 1 × 10⁻¹² mol/L

      Misconception: Thinks pure water contains no ions at all.

      Feedback from the catalogue

      Even in pure water, water molecules pass protons to one another: 2H2O⇌H3O++OH−\mathrm{2H_2O \rightleftharpoons H_3O^+ + OH^-}⁠. That equilibrium lies far to the left, but not all the way: at 25 °C there are 10−710^{-7}⁠ moles of each ion per litre. Because of that little, pure water conducts electricity, very weakly.

    • 7 mol/L ± 0.01 mol/L

      Misconception: Gives a pH or pOH number where a concentration in mol/L is asked for.

      Feedback from the catalogue

      pH is not a concentration: it is the concentration’s exponent, with the sign flipped. pH=3\mathrm{pH} = 3⁠ means [H3O+]=10−3 mol/L[\mathrm{H_3O^+}] = 10^{-3}\ \mathrm{mol/L}⁠. To go from pH to concentration, raise 1010⁠ to minus the pH.

    Feedback for a right answer

    10−7 mol/L10^{-7}\ \mathrm{mol/L}⁠: about one molecule in every five hundred million has passed on a proton. And there is exactly as much OH−\mathrm{OH^-}⁠, so the water is neutral.

    Hint

    [H3O+]=10−pH[\mathrm{H_3O^+}] = 10^{-\mathrm{pH}}⁠. You can type 1e-7.

    Worked solution

    1. pH=−log⁡[H3O+]\mathrm{pH} = -\log[\mathrm{H_3O^+}]⁠, so [H3O+]=10−pH[\mathrm{H_3O^+}] = 10^{-\mathrm{pH}}⁠.
    2. [H3O+]=10−7 mol/L[\mathrm{H_3O^+}] = 10^{-7}\ \mathrm{mol/L}⁠.
    3. In pure water each H3O+\mathrm{H_3O^+}⁠ forms with an OH−\mathrm{OH^-}⁠, so [OH−]=10−7[\mathrm{OH^-}] = 10^{-7}⁠ too, and 10−7×10−7=10−1410^{-7} \times 10^{-7} = 10^{-14}⁠.

    If you answered 00⁠: even pure water holds ions. If you answered 77⁠, you gave the pH, not the concentration.

  3. Step 3 of 5

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    Strong and weak

    Practice · Choose

    Question

    Two beakers hold acid at 0.1 mol/L: one hydrochloric acid, HCl\mathrm{HCl}⁠, the other ethanoic acid, CH3COOH\mathrm{CH_3COOH}⁠, the acid in vinegar. The first has pH 1.01.0⁠, the second 2.92.9⁠. Why?

    Correct answer

    • Correct HCl\mathrm{HCl}⁠ splits almost entirely into ions in water, and ethanoic acid only a small part of it

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    The Scene at this step

    pH
    2.9
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    • Correct HCl\mathrm{HCl}⁠ splits almost entirely into ions in water, and ethanoic acid only a small part of it

    • Wrong The HCl\mathrm{HCl}⁠ beaker holds more acid in each litre

      Misconception: Confuses a strong acid with a concentrated one, and a weak acid with a dilute one.

      Feedback from the catalogue

      Strong and concentrated are different properties. A strong acid, like HCl\mathrm{HCl}⁠, splits almost completely into ions in water; a weak acid, like ethanoic acid, splits only partly, because it reaches an equilibrium. Concentration is how much acid there is per litre. Very dilute hydrochloric acid is still strong, and concentrated vinegar is still weak.

    • Wrong Ethanoic acid gives no H3O+\mathrm{H_3O^+}⁠ at all; its pH comes from the water

      Feedback

      Water alone gives pH 77⁠. A pH of 2.92.9⁠ says the ethanoic acid did give H3O+\mathrm{H_3O^+}⁠, about thirteen thousand times what water gives, only less than hydrochloric acid.

    Feedback for a right answer

    HCl\mathrm{HCl}⁠ is a strong acid: every molecule gives a proton to water, [H3O+]=0.1[\mathrm{H_3O^+}] = 0.1⁠. Ethanoic acid is weak: it reaches an equilibrium, CH3COOH+H2O⇌CH3COO−+H3O+\mathrm{CH_3COOH + H_2O \rightleftharpoons CH_3COO^- + H_3O^+}⁠, in which only about 1%1\%⁠ of it splits.

    Hint

    Both have the same concentration. What differs between them?

    Worked solution

    1. pH 1.01.0⁠: [H3O+]=10−1=0.1[\mathrm{H_3O^+}] = 10^{-1} = 0.1⁠, all the acid.
    2. pH 2.92.9⁠: [H3O+]=10−2.9=0.0013[\mathrm{H_3O^+}] = 10^{-2.9} = 0.0013⁠, about 1.3%1.3\%⁠ of the acid.
    3. The concentrations are equal, so the difference is in strength: how far the acid splits into ions.

    “Strong” and “concentrated” are two different questions: how much splits, and how much there is.

  4. Step 4 of 5

    Open this step

    Bases

    Practice · Choose

    Question

    pH now stands at 11. What is true about the solution?

    Correct answer

    • Correct It holds more OH−\mathrm{OH^-}⁠ than H3O+\mathrm{H_3O^+}⁠, and the product of their concentrations is still 10−1410^{-14}⁠

    Setup, choices and feedback

    The Scene at this step

    pH
    11
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    Shown in a random order.

    • Correct It holds more OH−\mathrm{OH^-}⁠ than H3O+\mathrm{H_3O^+}⁠, and the product of their concentrations is still 10−1410^{-14}⁠

    • Wrong It holds no H3O+\mathrm{H_3O^+}⁠ at all

      Misconception: Thinks an acidic solution holds no OH⁻ at all, or a basic one no H₃O⁺.

      Feedback from the catalogue

      Every solution in water holds both hydronium ions, H3O+\mathrm{H_3O^+}⁠, and hydroxide ions, OH−\mathrm{OH^-}⁠, because water itself is always splitting a little. What makes a solution acidic is which there is more of: in an acidic solution [H3O+]>[OH−][\mathrm{H_3O^+}] > [\mathrm{OH^-}]⁠, and always [H3O+][OH−]=10−14[\mathrm{H_3O^+}][\mathrm{OH^-}] = 10^{-14}⁠ at 25 °C.

    • Wrong It holds no ions: a base is the opposite of an acid

      Misconception: Thinks pure water contains no ions at all.

      Feedback from the catalogue

      Even in pure water, water molecules pass protons to one another: 2H2O⇌H3O++OH−\mathrm{2H_2O \rightleftharpoons H_3O^+ + OH^-}⁠. That equilibrium lies far to the left, but not all the way: at 25 °C there are 10−710^{-7}⁠ moles of each ion per litre. Because of that little, pure water conducts electricity, very weakly.

    Feedback for a right answer

    At pH 1111⁠: [H3O+]=10−11[\mathrm{H_3O^+}] = 10^{-11}⁠ and [OH−]=10−3[\mathrm{OH^-}] = 10^{-3}⁠. A base, such as sodium hydroxide, NaOH→Na++OH−\mathrm{NaOH \rightarrow Na^+ + OH^-}⁠, or ammonia, NH3+H2O⇌NH4++OH−\mathrm{NH_3 + H_2O \rightleftharpoons NH_4^+ + OH^-}⁠, adds OH−\mathrm{OH^-}⁠, and water’s equilibrium shrinks H3O+\mathrm{H_3O^+}⁠ to match.

    Hint

    Look at the two ions’ bars in the second chart.

    Worked solution

    1. [H3O+]=10−11[\mathrm{H_3O^+}] = 10^{-11}⁠.
    2. [OH−]=10−1410−11=10−3[\mathrm{OH^-}] = \dfrac{10^{-14}}{10^{-11}} = 10^{-3}⁠.
    3. 10−3>10−1110^{-3} > 10^{-11}⁠: the solution is basic, and both ions are in it.
  5. Step 5 of 5

    Open this step

    The ion product

    Practice · Calculate

    Question

    At pH 33⁠, [H3O+]=10−3 mol/L[\mathrm{H_3O^+}] = 10^{-3}\ \mathrm{mol/L}⁠. What is [OH−][\mathrm{OH^-}]⁠?

    Correct answer

    1 × 10⁻¹¹ mol/L ± 3%

    Setup, choices and feedback

    The Scene at this step

    pH
    3fixed
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    offdefault
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    Accepted within
    ± 3%
    Computed from the Scene at this step’s setting
    'acid-base': OH⁻ concentration (10^(pH − 14) mol/L)/nodes/beaker/outputs/hydroxide

    Any unit of the same quantity is accepted; it is converted before checking.

    Wrong answers it recognises

    • 11 mol/L ± 0.01 mol/L

      Misconception: Gives a pH or pOH number where a concentration in mol/L is asked for.

      Feedback from the catalogue

      pH is not a concentration: it is the concentration’s exponent, with the sign flipped. pH=3\mathrm{pH} = 3⁠ means [H3O+]=10−3 mol/L[\mathrm{H_3O^+}] = 10^{-3}\ \mathrm{mol/L}⁠. To go from pH to concentration, raise 1010⁠ to minus the pH.

    • 0 mol/L ± 1 × 10⁻¹⁵ mol/L

      Misconception: Thinks an acidic solution holds no OH⁻ at all, or a basic one no H₃O⁺.

      Feedback from the catalogue

      Every solution in water holds both hydronium ions, H3O+\mathrm{H_3O^+}⁠, and hydroxide ions, OH−\mathrm{OH^-}⁠, because water itself is always splitting a little. What makes a solution acidic is which there is more of: in an acidic solution [H3O+]>[OH−][\mathrm{H_3O^+}] > [\mathrm{OH^-}]⁠, and always [H3O+][OH−]=10−14[\mathrm{H_3O^+}][\mathrm{OH^-}] = 10^{-14}⁠ at 25 °C.

    Feedback for a right answer

    10−1410−3=10−11 mol/L\dfrac{10^{-14}}{10^{-3}} = 10^{-11}\ \mathrm{mol/L}⁠. Very little, but not zero: a litre beaker holds about 6×10126 \times 10^{12}⁠ hydroxide ions.

    Hint

    [H3O+][OH−]=10−14[\mathrm{H_3O^+}][\mathrm{OH^-}] = 10^{-14}⁠.

    Worked solution

    1. [H3O+][OH−]=10−14[\mathrm{H_3O^+}][\mathrm{OH^-}] = 10^{-14}⁠.
    2. [OH−]=10−1410−3[\mathrm{OH^-}] = \dfrac{10^{-14}}{10^{-3}}⁠.
    3. [OH−]=10−14−(−3)=10−11 mol/L[\mathrm{OH^-}] = 10^{-14 - (-3)} = 10^{-11}\ \mathrm{mol/L}⁠.

    If you answered 1111⁠, you gave the pOH, the exponent with its sign flipped, not the concentration.

Lesson 2 of 4 · About 25 minutes

The pH scale

pH as a logarithm: minus the exponent of the hydronium concentration, one step that is ten times, working out pH from a concentration and back, dilution, and bases on the same scale.

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The 6 steps and their answers
  1. Step 1 of 6

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    Minus the logarithm

    Practice · Reach the target

    Question

    Change pH so that the beaker holds [H3O+]=10−4 mol/L[\mathrm{H_3O^+}] = 10^{-4}\ \mathrm{mol/L}⁠, then press Check.

    Goal

    • 0.0001 mol/L ± 5%

      At the start of the step: 1 × 10⁻⁷ mol/L

    Setup, choices and feedback

    The Scene at this step

    pH
    7
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    Read from the Scene at
    'acid-base': H₃O⁺ concentration (10^−pH mol/L)/nodes/beaker/outputs/hydronium

    One setting that reaches it

    pH
    4
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    off

    Feedback for a right answer

    pH 44⁠, about like tomato juice. The minus in the definition turns the exponent −4-4⁠ into the positive number 44⁠.

    Feedback for a wrong answer

    Not yet. The pH is the concentration’s exponent, with the sign flipped.

    Hint

    pH=−log⁡[H3O+]\mathrm{pH} = -\log[\mathrm{H_3O^+}]⁠.

    Worked solution

    1. pH=−log⁡(10−4)\mathrm{pH} = -\log(10^{-4})⁠.
    2. log⁡(10−4)=−4\log(10^{-4}) = -4⁠.
    3. pH=4\mathrm{pH} = 4⁠: set pH to 4.0.
  2. Step 2 of 6

    Open this step

    Powers of ten

    Practice · Predict, then look

    Question

    pH stands at 4. How many times more H3O+\mathrm{H_3O^+}⁠ ions will the beaker hold at pH 3?

    Correct answer

    • Correct Ten times

    Setup, choices and feedback

    The Scene at this step

    pH
    4fixed
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    Choices

    Once the prediction is locked in, the Scene changes

    pH
    3fixed
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    The Scene then shows: 0.001 mol/L · 'acid-base': H₃O⁺ concentration (10^−pH mol/L)/nodes/beaker/outputs/hydronium

    A prediction is never marked as a failure: the learner sees the outcome and the explanation either way.

    Feedback for a right answer

    Ten times: from 10−410^{-4}⁠ to 10−310^{-3}⁠. In the second chart the H3O+\mathrm{H_3O^+}⁠ bar climbs one square, because each square is a power of ten.

    Worked solution

    1. At pH 44⁠: [H3O+]=10−4[\mathrm{H_3O^+}] = 10^{-4}⁠.
    2. At pH 33⁠: [H3O+]=10−3[\mathrm{H_3O^+}] = 10^{-3}⁠.
    3. The ratio: 10−310−4=10\dfrac{10^{-3}}{10^{-4}} = 10⁠.

    The pH scale is a logarithmic scale, like the Richter scale for earthquakes: each step multiplies, it does not add.

  3. Step 3 of 6

    Open this step

    How many times more acidic

    Practice · Calculate

    Question

    How many times more H3O+\mathrm{H_3O^+}⁠ ions does a solution at pH 44⁠ hold than one at pH 88⁠?

    Correct answer

    10000 ± 0.1%

    Setup, choices and feedback

    The Scene at this step

    pH
    4
    Labels
    offdefault
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    Accepted within
    ± 0.1%
    A fixed value in the question

    Wrong answers it recognises

    Feedback for a right answer

    108−4=104=10 00010^{8-4} = 10^4 = 10\,000⁠. Not twice: a solution at pH 44⁠ is ten thousand times more acidic, though the number is only half.

    Hint

    Four steps of pH, each one ten times.

    Worked solution

    1. pH 44⁠: [H3O+]=10−4[\mathrm{H_3O^+}] = 10^{-4}⁠. pH 88⁠: [H3O+]=10−8[\mathrm{H_3O^+}] = 10^{-8}⁠.
    2. 10−410−8=10−4−(−8)=104\dfrac{10^{-4}}{10^{-8}} = 10^{-4-(-8)} = 10^4⁠.
    3. 10 00010\,000⁠ times.

    If you answered 22⁠, you divided the pH numbers. The pH is an exponent, so subtract the exponents and raise 1010⁠ to the difference.

  4. Step 4 of 6

    Open this step

    From a concentration to pH

    Practice · Calculate

    Question

    In lemon juice [H3O+]=2.5×10−3 mol/L[\mathrm{H_3O^+}] = 2.5 \times 10^{-3}\ \mathrm{mol/L}⁠. What is its pH? (Two decimal places.)

    Correct answer

    2.6 ± 0.02

    Setup, choices and feedback

    The Scene at this step

    pH
    7
    Labels
    offdefault
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    Accepted within
    ± 0.02
    A fixed value in the question

    Wrong answers it recognises

    • -2.6 ± 0.02

      Misconception: Forgets the minus in pH = −log[H₃O⁺], giving a negative pH for an ordinary acid.

      Feedback from the catalogue

      pH=−log⁡[H3O+]\mathrm{pH} = -\log[\mathrm{H_3O^+}]⁠. The concentrations are below one, so their logarithm is negative, and the minus makes it positive: log⁡(2.5×10−3)=−2.60\log(2.5 \times 10^{-3}) = -2.60⁠, so pH=2.60\mathrm{pH} = 2.60⁠.

    • 3 ± 0.02

      Misconception: Gives a pH or pOH number where a concentration in mol/L is asked for.

      Feedback from the catalogue

      pH is not a concentration: it is the concentration’s exponent, with the sign flipped. pH=3\mathrm{pH} = 3⁠ means [H3O+]=10−3 mol/L[\mathrm{H_3O^+}] = 10^{-3}\ \mathrm{mol/L}⁠. To go from pH to concentration, raise 1010⁠ to minus the pH.

    Feedback for a right answer

    pH=−log⁡(0.0025)=2.60\mathrm{pH} = -\log(0.0025) = 2.60⁠. Between 22⁠ and 33⁠, because the concentration is between 10−310^{-3}⁠ and 10−210^{-2}⁠; nearer 33⁠, because on a log scale 2.52.5⁠ is nearer 11⁠ than 1010⁠.

    Hint

    pH=−log⁡(2.5×10−3)\mathrm{pH} = -\log(2.5 \times 10^{-3})⁠. On a calculator: log(0.0025).

    Worked solution

    1. log⁡(2.5×10−3)=log⁡2.5+log⁡10−3=0.40−3=−2.60\log(2.5 \times 10^{-3}) = \log 2.5 + \log 10^{-3} = 0.40 - 3 = -2.60⁠.
    2. pH=−(−2.60)=2.60\mathrm{pH} = -(-2.60) = 2.60⁠.

    If you got −2.60-2.60⁠, you forgot the minus in the definition. If you answered 33⁠, you took only the exponent and forgot the 2.52.5⁠.

  5. Step 5 of 6

    Open this step

    Dilution

    Practice · Calculate

    Question

    To 10 mL of 0.1 mol/L hydrochloric acid, at pH 11⁠, you add water up to 1000 mL. What is the pH now?

    Correct answer

    3 ± 0.02

    Setup, choices and feedback

    The Scene at this step

    pH
    1
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    ± 0.02
    A fixed value in the question

    Wrong answers it recognises

    Feedback for a right answer

    [H3O+][\mathrm{H_3O^+}]⁠ fell a hundred times, from 10−110^{-1}⁠ to 10−310^{-3}⁠, and the pH rose from 11⁠ to 33⁠. To dilute all the way to pH 77⁠ would take a millionfold dilution, and by then the acid no longer decides: the water itself does.

    Hint

    How many times does the concentration fall, and how many steps of pH is that?

    Worked solution

    1. The volume grows from 1010⁠ to 10001000⁠ mL, 100100⁠ times, so the concentration falls 100100⁠ times: 0.1100=10−3 mol/L\dfrac{0.1}{100} = 10^{-3}\ \mathrm{mol/L}⁠.
    2. pH=−log⁡(10−3)=3\mathrm{pH} = -\log(10^{-3}) = 3⁠.

    100=102100 = 10^2⁠ times in concentration is two steps of pH.

  6. Step 6 of 6

    Open this step

    Bases on the same scale

    Practice · Calculate

    Question

    What is the pH of a 0.01 mol/L solution of sodium hydroxide, NaOH\mathrm{NaOH}⁠?

    Correct answer

    12 ± 0.02

    Setup, choices and feedback

    The Scene at this step

    pH
    7
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    Accepted within
    ± 0.02
    A fixed value in the question

    Wrong answers it recognises

    • 2 ± 0.02

      Misconception: Takes −log[OH⁻] as the pH of a basic solution, giving the pOH instead.

      Feedback from the catalogue

      Minus the logarithm of [OH−][\mathrm{OH^-}]⁠ is the pOH, not the pH. Because [H3O+][OH−]=10−14[\mathrm{H_3O^+}][\mathrm{OH^-}] = 10^{-14}⁠, pH+pOH=14\mathrm{pH} + \mathrm{pOH} = 14⁠. For 0.01 mol/L sodium hydroxide: pOH=2\mathrm{pOH} = 2⁠, so pH=12\mathrm{pH} = 12⁠.

    Feedback for a right answer

    pH 1212⁠: [OH−]=10−2[\mathrm{OH^-}] = 10^{-2}⁠, so [H3O+]=10−12[\mathrm{H_3O^+}] = 10^{-12}⁠. Move pH to 12 and check in the chart.

    Hint

    NaOH\mathrm{NaOH}⁠ is a strong base: [OH−]=0.01[\mathrm{OH^-}] = 0.01⁠. From there to [H3O+][\mathrm{H_3O^+}]⁠.

    Worked solution

    1. A strong base splits completely: [OH−]=0.01=10−2[\mathrm{OH^-}] = 0.01 = 10^{-2}⁠.
    2. [H3O+]=10−1410−2=10−12[\mathrm{H_3O^+}] = \dfrac{10^{-14}}{10^{-2}} = 10^{-12}⁠.
    3. pH=12\mathrm{pH} = 12⁠. (Or: pOH=2\mathrm{pOH} = 2⁠ and pH=14−2=12\mathrm{pH} = 14 - 2 = 12⁠.)

    If you answered 22⁠, you gave the pOH.

Lesson 3 of 4 · About 30 minutes

Neutralisation and titration

An acid and a base that give a salt and water, a pH curve that leaps near the equivalence point, and titrating drop by drop to measure an unknown concentration.

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The 5 steps and their answers
  1. Step 1 of 5

    Open this step

    Neutralisation

    Practice · Choose

    Question

    The flask holds hydrochloric acid, and the burette sodium hydroxide. What forms when they react?

    Correct answer

    • Correct A salt and water: HCl+NaOH→NaCl+H2O\mathrm{HCl + NaOH \rightarrow NaCl + H_2O}⁠

    Setup, choices and feedback

    The Scene at this step

    Volume added
    0 mL
    Curve so far / Whole curve
    Curve so far

    Choices

    Shown in a random order.

    • Correct A salt and water: HCl+NaOH→NaCl+H2O\mathrm{HCl + NaOH \rightarrow NaCl + H_2O}⁠

    • Wrong Nothing: the acid and the base cancel out and disappear

      Misconception: Thinks neutralisation makes the acid and base disappear, leaving nothing behind.

      Feedback from the catalogue

      In neutralisation no atoms vanish: H3O+\mathrm{H_3O^+}⁠ and OH−\mathrm{OH^-}⁠ ions join into water, and the other ions, Na+\mathrm{Na^+}⁠ and Cl−\mathrm{Cl^-}⁠, stay in the solution. Boil off the water and table salt is left. An acid and a base give a salt and water.

    • Wrong Hydrogen, bubbling out of the flask

      Feedback

      Hydrogen forms when an acid reacts with a metal, like magnesium. With a base it gives water.

    Feedback for a right answer

    This is neutralisation: H3O++OH−→2H2O\mathrm{H_3O^+ + OH^- \rightarrow 2H_2O}⁠. The Na+\mathrm{Na^+}⁠ and Cl−\mathrm{Cl^-}⁠ ions take no part and stay in the solution: salt water. The reaction gives out heat, about 57 kJ per mole of water.

    Hint

    What do H3O+\mathrm{H_3O^+}⁠ and OH−\mathrm{OH^-}⁠ do when they meet? And what happens to the Na+\mathrm{Na^+}⁠ and Cl−\mathrm{Cl^-}⁠?

    Worked solution

    1. The acid gives H3O+\mathrm{H_3O^+}⁠ and Cl−\mathrm{Cl^-}⁠; the base gives Na+\mathrm{Na^+}⁠ and OH−\mathrm{OH^-}⁠.
    2. H3O+\mathrm{H_3O^+}⁠ and OH−\mathrm{OH^-}⁠ join into water.
    3. Na+\mathrm{Na^+}⁠ and Cl−\mathrm{Cl^-}⁠ are left: a solution of the salt NaCl\mathrm{NaCl}⁠.
  2. Step 2 of 5

    Open this step

    The curve

    Practice · Predict, then look

    Question

    The flask holds 25 mL of hydrochloric acid, and the burette sodium hydroxide, both at 0.1 mol/L. How will the pH change as you add up to 30 mL?

    Correct answer

    • Correct Very slowly at first, then a big jump near 25 mL

    Setup, choices and feedback

    The Scene at this step

    Volume added
    0 mLfixed
    Curve so far / Whole curve
    Curve so farfixed

    Choices

    • Correct Very slowly at first, then a big jump near 25 mL

    • Wrong At a steady rate, a few tenths for each millilitre

      Misconception: Expects the pH to rise steadily as base is added during a titration.

      Feedback from the catalogue

      While acid is in excess, the pH is set by what is left of it, and it rises slowly: neutralising half the acid moves it by less than half a unit. Only near the equivalence point, with the acid nearly gone, does one drop change the concentration thousands of times, and the pH leaps several units at once.

    • Wrong Very fast at first, then slowly

      Feedback

      At first there is plenty of acid, and the first drops neutralise only a small share of it: the pH hardly moves. Only when the acid is nearly gone does each drop change a lot.

    Once the prediction is locked in, the Scene changes

    Volume added
    30 mLfixed
    Curve so far / Whole curve
    Whole curvefixed

    The Scene then shows: 11.96 · PH of the flask/nodes/rig/outputs/pH

    A prediction is never marked as a failure: the learner sees the outcome and the explanation either way.

    Feedback for a right answer

    Up to 24 mL the pH rises only from 1.01.0⁠ to 2.72.7⁠. Then, between 24.9 and 25.1 mL, two drops, it leaps from 3.73.7⁠ to 10.310.3⁠, and the flask turns pink. After that it flattens again, around 1212⁠.

    Worked solution

    1. At 24 mL there is 2.5−2.4=0.12.5 - 2.4 = 0.1⁠ millimole of acid left in 49 mL: [H3O+]=0.002[\mathrm{H_3O^+}] = 0.002⁠, pH=2.7\mathrm{pH} = 2.7⁠.
    2. At 24.9 mL there is 0.010.01⁠ millimole left: pH=3.7\mathrm{pH} = 3.7⁠.
    3. At 25.0 mL the acid and base are equal: pH=7\mathrm{pH} = 7⁠.
    4. At 25.1 mL there is 0.010.01⁠ millimole of OH−\mathrm{OH^-}⁠ in excess: pOH=3.7\mathrm{pOH} = 3.7⁠, pH=10.3\mathrm{pH} = 10.3⁠.

    Each drop near the equivalence point changes the concentration ten times or more, so the pH leaps.

  3. Step 3 of 5

    Open this step

    The equivalence point

    Practice · Calculate

    Question

    Now the flask holds 20 mL of 0.10 mol/L hydrochloric acid, and the burette 0.08 mol/L sodium hydroxide. What volume of base will exactly neutralise all the acid?

    Correct answer

    25 mL ± 0.1 mL

    Setup, choices and feedback

    The Scene at this step

    Volume added
    0 mL
    Curve so far / Whole curve
    Curve so farfixed
    Other settings
    Sample volume/nodes/rig/props/sampleVolume = 20
    Other settings
    Base concentration/nodes/rig/props/baseConcentration = 0.08
    Accepted within
    ± 0.1 mL
    Computed from the Scene at this step’s setting
    Volume of titrant that exactly neutralises the sample/nodes/rig/outputs/equivalenceVolume

    Any unit of the same quantity is accepted; it is converted before checking.

    Wrong answers it recognises

    Feedback for a right answer

    25 mL: 0.10×200.08=25\dfrac{0.10 \times 20}{0.08} = 25⁠. The base is more dilute than the acid, so you need more of it. Choose Whole curve under Look inside to see the equivalence point on the chart.

    Hint

    At the equivalence point the moles of base equal the moles of acid: caVa=cbVbc_a V_a = c_b V_b⁠.

    Worked solution

    1. Moles of acid: n=c×V=0.10×0.020=0.0020n = c \times V = 0.10 \times 0.020 = 0.0020⁠ mol, that is 2.02.0⁠ millimoles.
    2. HCl+NaOH\mathrm{HCl + NaOH}⁠ react 1:11 : 1⁠, so you need 2.02.0⁠ millimoles of base.
    3. Vb=ncb=2.0 mmol0.08 mol/L=25 mLV_b = \dfrac{n}{c_b} = \dfrac{2.0\ \mathrm{mmol}}{0.08\ \mathrm{mol/L}} = 25\ \mathrm{mL}⁠.

    If you answered 1616⁠, you turned the ratio of concentrations upside down. If 2020⁠, you assumed equal volumes neutralise each other.

  4. Step 4 of 5

    Open this step

    Running it in

    Practice · Reach the target

    Question

    Again 25 mL of hydrochloric acid and sodium hydroxide, both at 0.1 mol/L. Change Volume added until you have added exactly enough base to neutralise all the acid, then press Check.

    Goal

    • 1 ± 0.1

      At the start of the step: 0

    Setup, choices and feedback

    The Scene at this step

    Volume added
    0 mL
    Curve so far / Whole curve
    Curve so farfixed
    Read from the Scene at
    0 before equivalence, 1 at it (within 0.05 mL), 2 past it/nodes/rig/outputs/regime

    One setting that reaches it

    Volume added
    25 mL

    Feedback for a right answer

    At 25.0 mL: 2.52.5⁠ millimoles of acid and 2.52.5⁠ of base, and the pH is exactly 77⁠. Notice the flask is still colourless: phenolphthalein turns pink only with the next drop, at 25.1 mL. That is the end point, a drop after the equivalence point.

    Feedback for a wrong answer

    Not yet. How many millimoles of acid are in the flask, and how many millilitres of base hold the same number?

    Hint

    Do not wait for the colour: work out the volume from the moles.

    Worked solution

    1. In the flask: 0.1×25=2.50.1 \times 25 = 2.5⁠ millimoles of HCl\mathrm{HCl}⁠.
    2. In the burette: 0.10.1⁠ millimole in each millilitre.
    3. 2.50.1=25.0\dfrac{2.5}{0.1} = 25.0⁠: set Volume added to 25.0 mL.
  5. Step 5 of 5

    Open this step

    An acid of unknown concentration

    Practice · Calculate

    Question

    The flask holds 25.0 mL of hydrochloric acid of unknown concentration, and the burette 0.100 mol/L sodium hydroxide. Look inside at Whole curve shows the equivalence point. What is the acid’s concentration?

    Correct answer

    0.08 mol/L ± 0.002 mol/L

    Setup, choices and feedback

    The Scene at this step

    Volume added
    20 mLfixed
    Curve so far / Whole curve
    Whole curvefixed
    Other settings
    Acid concentration/nodes/rig/props/acidConcentration = 0.08
    Other settings
    Readings/nodes/rig/props/readings = false
    Accepted within
    ± 0.002 mol/L
    Computed from the Scene at this step’s setting
    Acid concentration/nodes/rig/props/acidConcentration

    Any unit of the same quantity is accepted; it is converted before checking.

    Wrong answers it recognises

    Feedback for a right answer

    0.080 mol/L: 20.0 mL of 0.100 mol/L base is 2.002.00⁠ millimoles, and they sit in 25.0 mL of acid. That is how titration is used in the lab: measuring an unknown concentration with a solution whose concentration is known.

    Hint

    Read the equivalence volume under the chart, and work out how many moles of base it holds.

    Worked solution

    1. The equivalence volume from the chart: 20.020.0⁠ mL.
    2. Moles of base: 0.100×20.0=2.000.100 \times 20.0 = 2.00⁠ millimoles; at 1:11 : 1⁠, that is also the millimoles of acid.
    3. ca=2.00 mmol25.0 mL=0.080 mol/Lc_a = \dfrac{2.00\ \mathrm{mmol}}{25.0\ \mathrm{mL}} = 0.080\ \mathrm{mol/L}⁠.

    If you got 0.1250.125⁠, you turned the ratio of volumes upside down: an acid that needs less base than its own volume is more dilute than the base.

Lesson 4 of 4 · About 25 minutes

Titration curves and indicators

A weak acid on the curve: a pH that climbs gradually, an equivalence point above 7 and the pKa half way. And how to choose an indicator that changes colour right on the steep part.

Open the lesson

The 5 steps and their answers
  1. Step 1 of 5

    Open this step

    A weak acid

    Practice · Predict, then look

    Question

    This time the flask holds ethanoic acid, a weak acid, at the same concentration and volume. What will the pH be at the equivalence point?

    Correct answer

    • Correct Above 77⁠

    Setup, choices and feedback

    The Scene at this step

    Acid in the flask
    Ethanoic acid (weak)fixed
    Indicator
    Phenolphthalein
    Volume added
    0 mL
    Curve so far / Whole curve
    Curve so farfixed

    Choices

    • Correct Above 77⁠

    • Wrong Exactly 77⁠: the acid and the base are equal

      Misconception: Thinks the pH at the equivalence point is always 7.

      Feedback from the catalogue

      At the equivalence point the amounts of acid and base are equal, but the solution is not always neutral. When a weak acid is neutralised its ion is left behind, ethanoate, CH3COO−\mathrm{CH_3COO^-}⁠, and that is a weak base that takes protons from water: the pH at equivalence is above 77⁠. With a weak base, like ammonia, it is below 77⁠. Only a strong acid with a strong base gives exactly 77⁠.

    • Wrong Below 77⁠: a weak acid leaves acid behind

      Feedback

      At the equivalence point all the acid has reacted. What is left is its ion, ethanoate, and that is slightly basic.

    Once the prediction is locked in, the Scene changes

    Volume added
    25 mL
    Curve so far / Whole curve
    Whole curvefixed

    The Scene then shows: 8.73 · PH at the equivalence point/nodes/rig/outputs/equivalencePH

    A prediction is never marked as a failure: the learner sees the outcome and the explanation either way.

    Feedback for a right answer

    8.78.7⁠. At the equivalence point the flask holds sodium ethanoate, and the ethanoate ion takes a few protons from water: CH3COO−+H2O⇌CH3COOH+OH−\mathrm{CH_3COO^- + H_2O \rightleftharpoons CH_3COOH + OH^-}⁠. The start differs too: 2.92.9⁠ instead of 1.01.0⁠, and the curve climbs gradually rather than leaping early.

    Worked solution

    1. At the equivalence point: 2.52.5⁠ millimoles of CH3COO−\mathrm{CH_3COO^-}⁠ in 50 mL, that is 0.05 mol/L0.05\ \mathrm{mol/L}⁠.
    2. Ethanoate is a weak base, with Kb=KwKa=10−141.74×10−5=5.8×10−10K_b = \dfrac{K_w}{K_a} = \dfrac{10^{-14}}{1.74 \times 10^{-5}} = 5.8 \times 10^{-10}⁠.
    3. [OH−]=Kb×0.05=5.4×10−6[\mathrm{OH^-}] = \sqrt{K_b \times 0.05} = 5.4 \times 10^{-6}⁠: pOH=5.3\mathrm{pOH} = 5.3⁠, pH=8.7\mathrm{pH} = 8.7⁠.

    Only when the acid and base are both strong is the equivalence point at pH 77⁠.

  2. Step 2 of 5

    Open this step

    Half way

    Practice · Calculate

    Question

    The equivalence volume is 25 mL. Change Volume added to 12.5 mL, half of it, and read the pH. What is the pKa\mathrm{p}K_a⁠ of ethanoic acid?

    Correct answer

    4.76 ± 0.05

    Setup, choices and feedback

    The Scene at this step

    Acid in the flask
    Ethanoic acid (weak)fixed
    Indicator
    Phenolphthalein
    Volume added
    0 mL
    Curve so far / Whole curve
    Whole curve
    Accepted within
    ± 0.05
    Computed from the Scene at this step’s setting
    PH half way to equivalence (the weak acid's pKa, or 14 − the weak base's pKb)/nodes/rig/outputs/halfEquivalencePH

    Wrong answers it recognises

    • 8.73 ± 0.05

      Misconception: Reads the pKa of a weak acid at the equivalence point rather than half way to it.

      Feedback from the catalogue

      The pKa is read half way to the equivalence point. There exactly half the acid has turned into its ion, [CH3COOH]=[CH3COO−][\mathrm{CH_3COOH}] = [\mathrm{CH_3COO^-}]⁠, so by Ka=[H3O+][CH3COO−][CH3COOH]K_a = \dfrac{[\mathrm{H_3O^+}][\mathrm{CH_3COO^-}]}{[\mathrm{CH_3COOH}]}⁠, [H3O+]=Ka[\mathrm{H_3O^+}] = K_a⁠ and pH=pKa\mathrm{pH} = \mathrm{p}K_a⁠. At the equivalence point there is hardly any acid left.

    Feedback for a right answer

    4.764.76⁠. Half way, [CH3COOH]=[CH3COO−][\mathrm{CH_3COOH}] = [\mathrm{CH_3COO^-}]⁠, and then [H3O+]=Ka[\mathrm{H_3O^+}] = K_a⁠. It is also the flattest part of the curve: a mixture of a weak acid and its ion is a buffer, which resists a change of pH.

    Hint

    Half way to equivalence, half the acid has turned into ethanoate.

    Worked solution

    1. Ka=[H3O+][CH3COO−][CH3COOH]K_a = \dfrac{[\mathrm{H_3O^+}][\mathrm{CH_3COO^-}]}{[\mathrm{CH_3COOH}]}⁠.
    2. At 12.5 mL half the acid has been neutralised: [CH3COO−]=[CH3COOH][\mathrm{CH_3COO^-}] = [\mathrm{CH_3COOH}]⁠, and they cancel.
    3. That leaves Ka=[H3O+]K_a = [\mathrm{H_3O^+}]⁠, so pKa=pH=4.76\mathrm{p}K_a = \mathrm{pH} = 4.76⁠.

    If you answered 8.78.7⁠, you read at the equivalence point, where there is hardly any acid left.

  3. Step 3 of 5

    Open this step

    The wrong indicator

    Practice · Predict, then look

    Question

    Methyl orange changes from red to yellow between pH 3.13.1⁠ and 4.44.4⁠. If you titrate the ethanoic acid with it instead of phenolphthalein, when will the flask turn yellow?

    Correct answer

    • Correct Long before the equivalence point, after a few millilitres

    Setup, choices and feedback

    The Scene at this step

    Acid in the flask
    Ethanoic acid (weak)fixed
    Indicator
    Phenolphthaleinfixed
    Volume added
    0 mL
    Curve so far / Whole curve
    Whole curve

    Choices

    • Correct Long before the equivalence point, after a few millilitres

    • Wrong At the equivalence point, at 25 mL: that is what an indicator is for

      Misconception: Thinks any indicator marks the equivalence point, whatever pH it changes colour at.

      Feedback from the catalogue

      An indicator changes colour over a pH range of its own, not at the equivalence point. It suits a titration only when its range falls on the steep part of the curve, where one drop moves the pH several units. With a weak acid the steep part runs from about 77⁠ to 1111⁠, so phenolphthalein (8.28.2⁠–1010⁠) suits, and methyl orange (3.13.1⁠–4.44.4⁠) changes colour far too early.

    • Wrong Never: methyl orange does not work with bases

      Feedback

      Methyl orange changes colour by pH, not by substance. Once the pH passes 4.44.4⁠, it is yellow.

    Once the prediction is locked in, the Scene changes

    Indicator
    Methyl orangefixed
    Volume added
    5 mL
    Curve so far / Whole curve
    Whole curve

    The Scene then shows: 1.949 mL · Volume added when the indicator is half changed (pH = pKIn)/nodes/rig/outputs/endPointVolume

    A prediction is never marked as a failure: the learner sees the outcome and the explanation either way.

    Feedback for a right answer

    At about 2 mL, before you have added a tenth of the base needed. Ethanoic acid’s pH passes 3.73.7⁠ early, and on the steep part, between 77⁠ and 1111⁠, methyl orange has long been yellow. An end point like that is worthless.

    Worked solution

    1. An indicator changes colour when the pH crosses its range, here 3.13.1⁠–4.44.4⁠.
    2. On the ethanoic acid curve the pH starts at 2.92.9⁠ and passes 3.73.7⁠ after only about 2 mL.
    3. The end point is far from the equivalence point, so methyl orange does not suit a weak acid.
  4. Step 4 of 5

    Open this step

    Choosing an indicator

    Practice · Choose

    Question

    Which indicator suits titrating ethanoic acid with sodium hydroxide?

    Correct answer

    • Correct Phenolphthalein, which changes between pH 8.28.2⁠ and 1010⁠

    Setup, choices and feedback

    The Scene at this step

    Acid in the flask
    Ethanoic acid (weak)
    Indicator
    Phenolphthalein
    Volume added
    0 mL
    Curve so far / Whole curve
    Whole curve

    Choices

    Shown in a random order.

    • Correct Phenolphthalein, which changes between pH 8.28.2⁠ and 1010⁠

    • Wrong Methyl orange, which changes between pH 3.13.1⁠ and 4.44.4⁠

      Misconception: Thinks any indicator marks the equivalence point, whatever pH it changes colour at.

      Feedback from the catalogue

      An indicator changes colour over a pH range of its own, not at the equivalence point. It suits a titration only when its range falls on the steep part of the curve, where one drop moves the pH several units. With a weak acid the steep part runs from about 77⁠ to 1111⁠, so phenolphthalein (8.28.2⁠–1010⁠) suits, and methyl orange (3.13.1⁠–4.44.4⁠) changes colour far too early.

    • Wrong Universal indicator, which changes all along the scale

      Feedback

      Universal indicator changes gradually, so it has no one moment when the colour flips. It is good for estimating pH, not for marking an end point.

    Feedback for a right answer

    Phenolphthalein. The equivalence point is at pH 8.78.7⁠, and the steep part runs from about 77⁠ to 1111⁠: phenolphthalein’s range sits on it, and the colour flips in one drop, at 25.0 mL.

    Hint

    Where is the steep part of the curve, and which range falls on it?

    Worked solution

    1. With a weak acid and a strong base, the equivalence point is above 77⁠ (8.78.7⁠).
    2. Choose an indicator whose range lies in the steep part, around the equivalence point.
    3. Phenolphthalein, 8.28.2⁠–1010⁠, suits. Methyl orange, 3.13.1⁠–4.44.4⁠, changes on the flat part, far too early.
  5. Step 5 of 5

    Open this step

    A weak base

    Practice · Choose

    Question

    Now the flask holds ammonia, a weak base, and the burette hydrochloric acid. The pH falls, and the equivalence point is at pH 5.35.3⁠. Which indicator suits?

    Correct answer

    • Correct Methyl orange, 3.13.1⁠–4.44.4⁠

    Setup, choices and feedback

    The Scene at this step

    Acid in the flask
    Hydrochloric acid (strong)hidden
    Indicator
    Phenolphthalein
    Volume added
    0 mL
    Curve so far / Whole curve
    Whole curve
    Other settings
    Base/nodes/rig/props/base = "weak"
    Other settings
    Titrant/nodes/rig/props/titrant = "acid"

    Choices

    Shown in a random order.

    • Correct Methyl orange, 3.13.1⁠–4.44.4⁠

    • Wrong Phenolphthalein, 8.28.2⁠–1010⁠

      Misconception: Thinks any indicator marks the equivalence point, whatever pH it changes colour at.

      Feedback from the catalogue

      An indicator changes colour over a pH range of its own, not at the equivalence point. It suits a titration only when its range falls on the steep part of the curve, where one drop moves the pH several units. With a weak acid the steep part runs from about 77⁠ to 1111⁠, so phenolphthalein (8.28.2⁠–1010⁠) suits, and methyl orange (3.13.1⁠–4.44.4⁠) changes colour far too early.

    • Wrong Neither: a weak base cannot be titrated

      Feedback

      It can, as long as you choose an indicator whose range falls on the steep part of the curve, here about 33⁠ to 77⁠.

    Feedback for a right answer

    Methyl orange. The steep part falls from about 77⁠ to 33⁠, and methyl orange changes colour on it, a drop after 25 mL. Phenolphthalein would lose its pink at about 10 mL, on the flat part.

    Hint

    Compare with the last question: everything is reversed.

    Worked solution

    1. Strong acid with weak base: the equivalence point is below 77⁠, because the ammonium ion, NH4+\mathrm{NH_4^+}⁠, is a weak acid.
    2. The steep part runs from about 77⁠ down to 33⁠.
    3. Methyl orange, 3.13.1⁠–4.44.4⁠, falls on it; phenolphthalein falls on the flat part at the start.

Across the unit · 15 misconceptions

Misconception catalogue

Each common mistake this unit recognises, in a few words. Open one for what the learner reads when an answer matches it, and where it is asked.

  • Thinks an acidic solution holds no OH⁻ at all, or a basic one no H₃O⁺.

    The learner reads

    Every solution in water holds both hydronium ions, H3O+\mathrm{H_3O^+}⁠, and hydroxide ions, OH−\mathrm{OH^-}⁠, because water itself is always splitting a little. What makes a solution acidic is which there is more of: in an acidic solution [H3O+]>[OH−][\mathrm{H_3O^+}] > [\mathrm{OH^-}]⁠, and always [H3O+][OH−]=10−14[\mathrm{H_3O^+}][\mathrm{OH^-}] = 10^{-14}⁠ at 25 °C.

  • Thinks pure water contains no ions at all.

    The learner reads

    Even in pure water, water molecules pass protons to one another: 2H2O⇌H3O++OH−\mathrm{2H_2O \rightleftharpoons H_3O^+ + OH^-}⁠. That equilibrium lies far to the left, but not all the way: at 25 °C there are 10−710^{-7}⁠ moles of each ion per litre. Because of that little, pure water conducts electricity, very weakly.

  • Confuses a strong acid with a concentrated one, and a weak acid with a dilute one.

    The learner reads

    Strong and concentrated are different properties. A strong acid, like HCl\mathrm{HCl}⁠, splits almost completely into ions in water; a weak acid, like ethanoic acid, splits only partly, because it reaches an equilibrium. Concentration is how much acid there is per litre. Very dilute hydrochloric acid is still strong, and concentrated vinegar is still weak.

  • Gives a pH or pOH number where a concentration in mol/L is asked for.

    The learner reads

    pH is not a concentration: it is the concentration’s exponent, with the sign flipped. pH=3\mathrm{pH} = 3⁠ means [H3O+]=10−3 mol/L[\mathrm{H_3O^+}] = 10^{-3}\ \mathrm{mol/L}⁠. To go from pH to concentration, raise 1010⁠ to minus the pH.

  • Treats the pH scale as linear: pH 4 is twice as acidic as pH 8, one step of pH is a fixed amount.

    The learner reads

    The pH scale is logarithmic: each step of one is ten times in [H3O+][\mathrm{H_3O^+}]⁠. From pH 88⁠ to pH 44⁠ is four steps, that is 104=10 00010^4 = 10\,000⁠: a solution at pH 44⁠ holds ten thousand times more hydronium ions, not twice as many.

  • Forgets the minus in pH = −log[H₃O⁺], giving a negative pH for an ordinary acid.

    The learner reads

    pH=−log⁡[H3O+]\mathrm{pH} = -\log[\mathrm{H_3O^+}]⁠. The concentrations are below one, so their logarithm is negative, and the minus makes it positive: log⁡(2.5×10−3)=−2.60\log(2.5 \times 10^{-3}) = -2.60⁠, so pH=2.60\mathrm{pH} = 2.60⁠.

  • Thinks diluting an acid with water does not change its pH.

    The learner reads

    Dilution lowers the concentration of every ion. Add water to a strong acid up to a hundred times its volume and [H3O+][\mathrm{H_3O^+}]⁠ falls a hundred times, that is 10210^2⁠, so the pH rises by two. The acid does not get weaker; it gets more dilute.

  • Takes −log[OH⁻] as the pH of a basic solution, giving the pOH instead.

    The learner reads

    Minus the logarithm of [OH−][\mathrm{OH^-}]⁠ is the pOH, not the pH. Because [H3O+][OH−]=10−14[\mathrm{H_3O^+}][\mathrm{OH^-}] = 10^{-14}⁠, pH+pOH=14\mathrm{pH} + \mathrm{pOH} = 14⁠. For 0.01 mol/L sodium hydroxide: pOH=2\mathrm{pOH} = 2⁠, so pH=12\mathrm{pH} = 12⁠.

  • Thinks neutralisation makes the acid and base disappear, leaving nothing behind.

    The learner reads

    In neutralisation no atoms vanish: H3O+\mathrm{H_3O^+}⁠ and OH−\mathrm{OH^-}⁠ ions join into water, and the other ions, Na+\mathrm{Na^+}⁠ and Cl−\mathrm{Cl^-}⁠, stay in the solution. Boil off the water and table salt is left. An acid and a base give a salt and water.

  • Expects the pH to rise steadily as base is added during a titration.

    The learner reads

    While acid is in excess, the pH is set by what is left of it, and it rises slowly: neutralising half the acid moves it by less than half a unit. Only near the equivalence point, with the acid nearly gone, does one drop change the concentration thousands of times, and the pH leaps several units at once.

  • Turns the ratio of concentrations upside down when working out a titration volume or concentration.

    The learner reads

    What becomes equal at the equivalence point is the number of moles: caVa=cbVbc_a V_a = c_b V_b⁠. A more dilute solution needs more volume, not less. Check the direction: if the base is more dilute than the acid, its volume must come out larger than the acid’s.

  • Thinks equal volumes of acid and base always neutralise each other.

    The learner reads

    Equal volumes neutralise each other only when the concentrations are equal. What has to match is the number of moles, n=c×Vn = c \times V⁠: 20 mL of 0.10 mol/L acid holds 2.02.0⁠ millimoles, and 0.08 mol/L base needs 25 mL for that.

  • Thinks the pH at the equivalence point is always 7.

    The learner reads

    At the equivalence point the amounts of acid and base are equal, but the solution is not always neutral. When a weak acid is neutralised its ion is left behind, ethanoate, CH3COO−\mathrm{CH_3COO^-}⁠, and that is a weak base that takes protons from water: the pH at equivalence is above 77⁠. With a weak base, like ammonia, it is below 77⁠. Only a strong acid with a strong base gives exactly 77⁠.

  • Reads the pKa of a weak acid at the equivalence point rather than half way to it.

    The learner reads

    The pKa is read half way to the equivalence point. There exactly half the acid has turned into its ion, [CH3COOH]=[CH3COO−][\mathrm{CH_3COOH}] = [\mathrm{CH_3COO^-}]⁠, so by Ka=[H3O+][CH3COO−][CH3COOH]K_a = \dfrac{[\mathrm{H_3O^+}][\mathrm{CH_3COO^-}]}{[\mathrm{CH_3COOH}]}⁠, [H3O+]=Ka[\mathrm{H_3O^+}] = K_a⁠ and pH=pKa\mathrm{pH} = \mathrm{p}K_a⁠. At the equivalence point there is hardly any acid left.

  • Thinks any indicator marks the equivalence point, whatever pH it changes colour at.

    The learner reads

    An indicator changes colour over a pH range of its own, not at the equivalence point. It suits a titration only when its range falls on the steep part of the curve, where one drop moves the pH several units. With a weak acid the steep part runs from about 77⁠ to 1111⁠, so phenolphthalein (8.28.2⁠–1010⁠) suits, and methyl orange (3.13.1⁠–4.44.4⁠) changes colour far too early.

Index