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Lesson 1 of 4

Hydrocarbons.

Why carbon builds chains, how to count the hydrogens of an alkane, what the first alkanes are called, and what forms when they burn.

Step 1 of 5 · Chains of carbon

Step 1 of 5

Chains of carbon

Organic chemistry is the chemistry of carbon compounds. There are millions of them, more than of all the other elements together, because carbon atoms bond to each other strongly and build chains, branches and rings. The Scene shows a chain of 6 carbons (grey) with hydrogens (white), as a ball-and-stick model. Look at each carbon and count the sticks coming out of it.

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Step 2 of 5

Counting hydrogens

Hydrocarbons are compounds of carbon and hydrogen only. When all the bonds between the carbons are single, the hydrocarbon is an alkane: each carbon holds as many hydrogens as it can, so it is called saturated. Carbon atoms and End group are now fixed.

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Step 3 of 5

The formula

You can count the hydrogens without drawing: each carbon has four bonds; the two end carbons use one of them on a neighbour, and each inner carbon uses two. That gives the general formula of the alkanes:

CnH2n+2\mathrm{C_nH_{2n+2}}⁠

End group is fixed at alkane, and Carbon atoms is free.

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Step 4 of 5

Names

An alkane’s name is a prefix that counts its carbons plus the ending -ane:

Carbons Name Formula
1 Methane CH4\mathrm{CH_4}⁠
2 Ethane C2H6\mathrm{C_2H_6}⁠
3 Propane C3H8\mathrm{C_3H_8}⁠
4 Butane C4H10\mathrm{C_4H_{10}}⁠
5 Pentane C5H12\mathrm{C_5H_{12}}⁠
6 Hexane C6H14\mathrm{C_6H_{14}}⁠

When the chain has one double bond, the hydrocarbon is an alkene, ending in -ene: ethene, propene, butene. It has two fewer hydrogens, CnH2n\mathrm{C_nH_{2n}}⁠.

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Step 5 of 5

Fuels

Cooking gas, petrol, diesel and paraffin are mostly alkanes. They react with oxygen and release a lot of energy: that is combustion. The Scene shows methane, the main part of natural gas.

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Still of the Organic chemistry and hydrocarbons 3D scene
Interactive scene

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Each step sets up the Scene for you, and a control marked “fixed” stays put for that step.

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Practice · Choose

How many covalent bonds does each carbon atom in the chain make?

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Practice · Calculate

The Scene shows hexane: a chain of 6 carbons, all single-bonded. How many hydrogen atoms does the molecule have?

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Practice · Reach the target

End group is fixed at alkane. Change Carbon atoms until the molecule has exactly 8 hydrogen atoms, then press Check.

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Practice · Choose

What is the name of the alkane C4H10\mathrm{C_4H_{10}}⁠, the gas in a lighter?

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Practice · Choose

What forms when methane, CH4\mathrm{CH_4}⁠, burns in air with plenty of oxygen?